Saturated nitrogen-containing heterocycles. 9. Synthesis and study of optically active pyrrolidinylalkanols and their tartrates
Autor: | I. N. Klochkova, V. G. Andrianov, G. K. Kravtsova, Yu. T. Strukhkov, S. A. Lazarev, M. V. Noritsina |
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Rok vydání: | 1983 |
Předmět: | |
Zdroj: | Chemistry of Heterocyclic Compounds. 19:180-183 |
ISSN: | 1573-8353 0009-3122 |
DOI: | 10.1007/bf00506431 |
Popis: | Optically active 3-(5-methyl-2-pyrrolidinyl)-1-propanols and their tartrates were synthesized. The stereochemical structures of the latter were established by x-ray diffraction analysis and PMR and IR spectroscopy. The absolute configuration was determined for (−)-cis-3-(1,5-dimethyl-2-pyrrolidinyl)-1-propanol (+)-bitartrate dihydrate, and the conformational and structural peculiarities of the pyrrolidinium cation and the tartrate anion were studied. |
Databáze: | OpenAIRE |
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