Saturated nitrogen-containing heterocycles. 9. Synthesis and study of optically active pyrrolidinylalkanols and their tartrates

Autor: I. N. Klochkova, V. G. Andrianov, G. K. Kravtsova, Yu. T. Strukhkov, S. A. Lazarev, M. V. Noritsina
Rok vydání: 1983
Předmět:
Zdroj: Chemistry of Heterocyclic Compounds. 19:180-183
ISSN: 1573-8353
0009-3122
DOI: 10.1007/bf00506431
Popis: Optically active 3-(5-methyl-2-pyrrolidinyl)-1-propanols and their tartrates were synthesized. The stereochemical structures of the latter were established by x-ray diffraction analysis and PMR and IR spectroscopy. The absolute configuration was determined for (−)-cis-3-(1,5-dimethyl-2-pyrrolidinyl)-1-propanol (+)-bitartrate dihydrate, and the conformational and structural peculiarities of the pyrrolidinium cation and the tartrate anion were studied.
Databáze: OpenAIRE