Rhodium-catalysed hydroamination-hydroarylation of norbornene with aniline, toluidines or diphenylamine
Autor: | Gérard Commenges, Jean-Jacques Brunet, Karine Philippot, Denis Neibecker |
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Rok vydání: | 1994 |
Předmět: | |
Zdroj: | Journal of Organometallic Chemistry. 469:221-228 |
ISSN: | 0022-328X |
Popis: | The condensation of aniline, toluidines or diphenylamine with norbornene tetrahydrofuran is promoted by a system generated from Li n Bu, ArNH 2 and [(PEt 3 ) 2 RhCl 2 ]. Aniline and m - and p -toluidines lead to a mixture of hydroamination and hydroarylation products whereas o -toluidine and diphenylamine lead to the hydroarylation product only. When conducted in the amine as solvent, the reaction is catalytic with respect to both lithium and rhodium. |
Databáze: | OpenAIRE |
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