Rhodium-catalysed hydroamination-hydroarylation of norbornene with aniline, toluidines or diphenylamine

Autor:	Gérard Commenges, Jean-Jacques Brunet, Karine Philippot, Denis Neibecker
Rok vydání:	1994
Předmět:	Chemistry Organic Chemistry Diphenylamine chemistry.chemical_element Toluidines Biochemistry Rhodium Inorganic Chemistry chemistry.chemical_compound Aniline Polymer chemistry Materials Chemistry Hydroamination Toluidine Physical and Theoretical Chemistry Tetrahydrofuran Norbornene
Zdroj:	Journal of Organometallic Chemistry. 469:221-228
ISSN:	0022-328X
Popis:	The condensation of aniline, toluidines or diphenylamine with norbornene tetrahydrofuran is promoted by a system generated from Li n Bu, ArNH 2 and [(PEt 3 ) 2 RhCl 2 ]. Aniline and m - and p -toluidines lead to a mixture of hydroamination and hydroarylation products whereas o -toluidine and diphenylamine lead to the hydroarylation product only. When conducted in the amine as solvent, the reaction is catalytic with respect to both lithium and rhodium.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2c4f72c27e4861230eed5c8c01c929c8 https://doi.org/10.1016/0022-328x(94)88076-x Zobrazit plný text záznamu