Kinetic Parameters of Thermal Decomposition of Furazano-1,2,3,4-Tetrazine-1,3-Dioxide and a Binary Solution Based on It
Autor: | N. V. Murav’ev, Vladimir E. Zarko, P. I. Kalmykov, Konstantin A. Monogarov, Alla N. Pivkina |
---|---|
Rok vydání: | 2019 |
Předmět: |
Materials science
General Chemical Engineering Kinetic analysis Thermal decomposition General Physics and Astronomy Energy Engineering and Power Technology Binary number Thermodynamics General Chemistry Activation energy Kinetic energy Tetrazine chemistry.chemical_compound Fuel Technology Differential scanning calorimetry chemistry |
Zdroj: | Combustion, Explosion, and Shock Waves. 55:629-631 |
ISSN: | 1573-8345 0010-5082 |
Popis: | The kinetic parameters of thermal decomposition of furazano-1,2,3,4-tetrazine-1,3-dioxide (FTDO) and the (75/25) FTDO/dinitrazapentane (DNP) system were experimentally investigated by differential scanning calorimetry. Kissinger kinetic analysis was performed using differential scanning calorimetry data obtained at heating rates of 0.1–5.0 K/min. The thermal decomposition of FTDO and the FTDO/DNP system is found to be a first-order reaction with an activation energy of 185 (FTDO) and 171 kJ/mol (FTDO/DNP). |
Databáze: | OpenAIRE |
Externí odkaz: |