Kinetic Parameters of Thermal Decomposition of Furazano-1,2,3,4-Tetrazine-1,3-Dioxide and a Binary Solution Based on It

Autor: N. V. Murav’ev, Vladimir E. Zarko, P. I. Kalmykov, Konstantin A. Monogarov, Alla N. Pivkina
Rok vydání: 2019
Předmět:
Zdroj: Combustion, Explosion, and Shock Waves. 55:629-631
ISSN: 1573-8345
0010-5082
Popis: The kinetic parameters of thermal decomposition of furazano-1,2,3,4-tetrazine-1,3-dioxide (FTDO) and the (75/25) FTDO/dinitrazapentane (DNP) system were experimentally investigated by differential scanning calorimetry. Kissinger kinetic analysis was performed using differential scanning calorimetry data obtained at heating rates of 0.1–5.0 K/min. The thermal decomposition of FTDO and the FTDO/DNP system is found to be a first-order reaction with an activation energy of 185 (FTDO) and 171 kJ/mol (FTDO/DNP).
Databáze: OpenAIRE