The structure of the product from reaction of an equimolar mixture of 1- and 2-bromomethylnaphthalenes with enneacarbonyldi-iron. A new π-complex with a trimethylenemethane-type ligand

Autor:	G. P. Zol'nikova, I. I. Kritskaya, A. N. Nesmeyanov, I. S. Astakhova, Yu. T. Struchkov
Rok vydání:	1970
Předmět:	chemistry.chemical_compound chemistry Ligand Product (mathematics) Atom Trimethylenemethane Alkylation Ring (chemistry) Photochemistry Benzene Medicinal chemistry
Zdroj:	J. Chem. Soc. D. :85-85
ISSN:	0577-6171
DOI:	10.1039/c29700000085
Popis:	The product of reaction of an equimolar mixture of 1- and 2-bromomethylnaphthalenes with Fe2(CO)9 is a new π-complex with a trimethylenemethane ligand which constitutes a part of the 2-naphthylmethyl group, the latter being alkylated in the 4-position of its co-ordinated benzene ring by the 1-naphthylmethyl radical, which does not participate in co-ordination with the iron atom.
Databáze:	OpenAIRE
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