| Autor: |
T Nakamura, Michiharu Wada, Shunsuke Ohtani, Ichiro Katayama, L Boesten, Kunihiro Okada |
| Rok vydání: |
2002 |
| Předmět: |
|
| Zdroj: |
Journal of Physics B: Atomic, Molecular and Optical Physics. 36:33-46 |
| ISSN: |
0953-4075 |
| DOI: |
10.1088/0953-4075/36/1/304 |
| Popis: |
The reactivity of laser-excited Ca+* ions in 3 2DJ (J = 3/2, 5/2) states with neutral H2O molecules was experimentally investigated. The reaction-product ions were sympathetically cooled by laser-cooled 40Ca+ ions and detected by laser-induced fluorescence mass spectroscopy. The reaction rate coefficient of Ca+*(DJ) + H2O → products was found to be 1.8(1) × 103 s−1 Pa−1 at an ion temperature of T = 3.1(1) × 103 K. The ion temperature dependence of the reaction rate coefficient was also measured for buffer-gas-cooled Ca+ ions. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
|
