Group 8 Metallomacrocycles – Synthesis, Characterization, and Stability

Autor: James M. Ludlow, Anthony Schultz, George R. Newkome, Rajarshi Sarkar, Charles N. Moorefield, Zaihong Guo, Chrys Wesdemiotis
Rok vydání: 2015
Předmět:
Zdroj: European Journal of Inorganic Chemistry. 2015:5662-5668
ISSN: 1099-0682
1434-1948
DOI: 10.1002/ejic.201500971
Popis: The one-step synthesis of the first homoleptic metallomacrocycle is reported. Characterization of the OsII complex, along with its FeII and RuII analogues, was accomplished by NMR spectroscopy, ESI-MS, TWIM-MS, gradient tandem-MS, CV, luminescence and UV/Vis spectroscopy. Center-of-mass collision energies, derived from gradient tandem-MS, reveal that the -based structures are more stable than those of .
Databáze: OpenAIRE
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