Group 8 Metallomacrocycles – Synthesis, Characterization, and Stability
Autor: | James M. Ludlow, Anthony Schultz, George R. Newkome, Rajarshi Sarkar, Charles N. Moorefield, Zaihong Guo, Chrys Wesdemiotis |
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Rok vydání: | 2015 |
Předmět: | |
Zdroj: | European Journal of Inorganic Chemistry. 2015:5662-5668 |
ISSN: | 1099-0682 1434-1948 |
DOI: | 10.1002/ejic.201500971 |
Popis: | The one-step synthesis of the first homoleptic metallomacrocycle is reported. Characterization of the OsII complex, along with its FeII and RuII analogues, was accomplished by NMR spectroscopy, ESI-MS, TWIM-MS, gradient tandem-MS, CV, luminescence and UV/Vis spectroscopy. Center-of-mass collision energies, derived from gradient tandem-MS, reveal that the -based structures are more stable than those of . |
Databáze: | OpenAIRE |
Externí odkaz: | |
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