Autor:	S. A. Lamotkin, A. I. Stankevich, E. D. Skakovskii, L. Yu. Tychinskaya, S. V. Rykov
Rok vydání:	2001
Předmět:	Arrhenius equation Chemistry Decarboxylation CIDNP Radical Thermal decomposition General Chemistry Photochemistry Peroxide symbols.namesake chemistry.chemical_compound Reaction rate constant symbols Polarization (electrochemistry)
Zdroj:	Russian Journal of General Chemistry. 71:614-622
ISSN:	1070-3632
DOI:	10.1023/a:1012399605722
Popis:	Kinetic measurements by 1H NMR spectroscopy and chemically induced dynamic nuclear polarization (CIDNP) effects were used to study thermolysis of solutions of acetyl propionyl peroxide in methanol-d4. It is found that the thermolysis may occur both by radical and by nonradical mechanisms. A scheme of the thermolysis is proposed. Parameters of the Arrhenius equation for the rate constants of the decomposition of the peroxide and the decarboxylation of acyloxyl radicals are obtained.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2c0d8e2cd63d8c68ae0d8bbd61bc9fc6 https://doi.org/10.1023/a:1012399605722 Zobrazit plný text záznamu Full text from SpringerLink