First order valence transition in Eu(Pd0.9Au0.1)2Si2: An X-ray diffraction study

Autor: V. Murgai, H. Jhans, B. Grier, Mark Croft, C. U. Segre, E. Kemly
Rok vydání: 1988
Předmět:
Zdroj: Solid State Communications. 66:1027-1030
ISSN: 0038-1098
DOI: 10.1016/0038-1098(88)90315-8
Popis: Temperature dependent x-ray diffraction measurements of Eu(Pd 0.9 Au 0.1 ) 2 Si 2 show two (200) Bragg diffraction peaks in the vicinity of the valence transition temperature determined by magnetic susceptibility measurements. As the temperature is lowered through the transition temperature, there is intensity transfer from one peak to the other, over a 50 K temperature range, indicating a discontinuous change in the lattice parameter a . This is a clear indication that spatially distinct macroscopic regions of the sample undergo a first order transition in contradiction with the recent interpretation of Mossbauer Effect measurements as being due to local environment effects. [1] The smearing of the transition temperature is interpreted as being due to sample inhomogeneities.
Databáze: OpenAIRE