ChemInform Abstract: Effect of Calcination on the Structure of Ni/MgO Catalyst: An X-Ray Diffraction Study

Autor: Adolfo Parmaliana, Francesco Arena, A. N. Shmakov, Francesco Frusteri, L. Plyasova
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 27
ISSN: 0931-7597
Popis: The progressive diffusion of Ni2+ ions into the MgO matrix, with the consequent formation of an NixMg(1–x)O solid solution, occurring during the air calcination of a 19% Ni/MgO catalyst in the range 400–1000 °C, has been monitored by X-ray diffraction (XRD) measurements using monochromatized non-doublet synchrotron radiation. A solid-state reaction model accounting for the NiO–MgO interaction in supported and mechanically mixed systems is discussed.
Databáze: OpenAIRE