Isotopic effect on electrochemical CO2 reduction activity and selectivity in H2O- and D2O-based electrolytes over palladium
| Autor: | Ji Hoon Lee, Sooyeon Hwang, Zhenhua Xie, Jingguang G. Chen, Brian M. Tackett |
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| Rok vydání: | 2020 |
| Předmět: |
Inorganic chemistry
Metals and Alloys Reduction Activity chemistry.chemical_element General Chemistry Electrolyte Electrochemistry Redox Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry Materials Chemistry Ceramics and Composites Hydrogen evolution Selectivity Palladium |
| Zdroj: | Chemical Communications. 56:106-108 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c9cc07611e |
| Popis: | The isotopic effect on the electrochemical CO2 reduction reaction (CO2RR) is investigated in this study. A higher CO2RR selectivity over its competing hydrogen evolution reaction was observed in D2O-based electrolytes compared with the H2O-based counterparts, which can be attributed to the lower [D+] concentration than [H+]. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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