The reaction of ferrocene derivatives with aryldiazoniums

Autor:	A. N. Nesmeyanov, É. G. Perevalova, N. A. Simukova, T. V. Nikitina, P. D. Reshetov
Rok vydání:	1961
Předmět:	chemistry.chemical_compound Ferrocene Chemistry Ferrocenemonocarboxylic acid Ethylferrocene Organic chemistry Ferrocene derivatives General Chemistry Dimethyl ester
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 10:67-71
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00909405
Popis:	1. The reaction of ferrocene derivatives with aryldiazoniums was studied. 2. On arylating p-tolylferrocene with p-tolyldiazonium, 1,1′-di-(p-tolyl)ferrocene was obtained. 3. On reacting methyl- and ethylferrocene with phenyldiazonium, a mixture of arylation products is formed, from which are obtained heteroannular methylphenylferrocene and ethylphenylferrocene. 4. Dipropionyl-, dibutyryl-, and dibenzoylferrocene react with p-nitrophenyldiazonium with rupture of the ferrocene nucleus, giving low yields of derivatives on a 1,2,3-oxadiazine. 5. On reacting the dimethyl ester of ferrocenedicarboxylic acid with p-nitrophenyldiazonium, both arylation and rupture of the ferrocene nucleus take place. 6. Monoacetylferrocene and the methyl ester of ferrocenemonocarboxylic acid are arylated on reacting with p-nitrophenyldiazonium.
Databáze:	OpenAIRE
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