Synthesis and Structures of MetallatedN-Heterocyclic Derivatives

Autor:	Alexander Rothenberger, Weifeng Shi, Lukasz Ponikiewski
Rok vydání:	2008
Předmět:	Chemistry Hydrogen bond Supramolecular chemistry chemistry.chemical_element Copper Medicinal chemistry Inorganic Chemistry Metal Phthalimide chemistry.chemical_compound Deprotonation visual_art visual_art.visual_art_medium Organic chemistry Heterocyclic derivatives
Zdroj:	Zeitschrift für anorganische und allgemeine Chemie. 634:1770-1774
ISSN:	1521-3749 0044-2313
DOI:	10.1002/zaac.200800044
Popis:	The synthesis and structures of five new compounds are reported. [Mg(6-Oq)2(phen)2] (1), [Na(phen)3][(6-HOq)(6-Oq)] (2), 1/∞[Cu(3-Opy)(3-HOpy)2(PPh3)]∞ (3), 1/∞[Cu2{μ-(6-Oq)}(PPh3)2]∞ (4) and [Cu2(pht)2(μ-dppm)2] (5) (6-HOq = 6-hydroxyquinoline; phen = 1,10-phenanthroline, 3-HOpy = 3-hydroxypyridine; Hpht = phthalimide; dppm = bis-(diphenylphosphino)methane) were prepared by deprotonation of N-heterocyclic aromatic compounds with metal alkoxides. 1–5 represent useful starting materials for investigating the supramolecular cordination chemistry of organic anhydrides.
Databáze:	OpenAIRE
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