ChemInform Abstract: The Valence States of Copernicium and Flerovium

Autor: Jeanet Conradie, Abhik Ghosh
Rok vydání: 2016
Předmět:
Zdroj: ChemInform. 47
ISSN: 0931-7597
Popis: Compared with its lighter congener HgF4, copernicium tetrafluoride, CnF4, is predicted to be significantly more stable with respect to decomposition to the elements. Tetravalent flerovium on the other hand is unlikely to be experimentally accessible, except possibly as FlF4. Because of the large 7p1/2–3/2 energy splitting, many divalent flerovium compounds are also expected to be thermodynamically unstable. The two dihalides FlF2 and FlCl2, however, are predicted to be thermodynamically stable; flerovium thus is not quite as noble as xenon, which is not known to form a chloride.
Databáze: OpenAIRE