Neutral Solvolysis of Acyl Carbon and the Temperature Dependence of the Kinetic Solvent Isotope Effect

Autor:	R. E. Robertson, B. Rossall
Rok vydání:	1975
Předmět:	Chemistry Organic Chemistry Inorganic chemistry Succinic anhydride chemistry.chemical_element General Chemistry Kinetic energy Catalysis Solvent Hydrolysis chemistry.chemical_compound Kinetic isotope effect Solvolysis Carbon
Zdroj:	Canadian Journal of Chemistry. 53:869-877
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v75-121
Popis:	The temperature dependence of the rate of hydrolysis of benzoic, phthalic, and succinic anhydrides have been determined in H2O and D2O under "neutral" conditions. Corresponding data have been obtained for methyl trifluoroacetate. While both series supposedly react by the same BAc2 mechanism, remarkable differences are made obvious by this investigation. Possible sources of such differences are proposed.
Databáze:	OpenAIRE
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