A oxygen-dependent reductive dechlorination of chloroform by (Bisdiphenylphosphinomethane)cobalthexacarbonyl Co2(CO)6(dppm)

Autor:	Meritxell Casadesus, Michael P. Coogan, Elenna Davies, Sarah Helen Oakley, Liling Ooi
Rok vydání:	2006
Předmět:	Chloroform Organic Chemistry Inorganic chemistry Halogenation chemistry.chemical_element Biochemistry Oxygen Inorganic Chemistry chemistry.chemical_compound chemistry Cobalt carbonyl Yield (chemistry) Materials Chemistry Reductive dechlorination Physical and Theoretical Chemistry Aeration
Zdroj:	Journal of Organometallic Chemistry. 691:3715-3717
ISSN:	0022-328X
DOI:	10.1016/j.jorganchem.2006.05.053
Popis:	The reaction of Co2(μ-dppm)(CO)6 with aerated chloroform affords [Co{Ph2P(O)CH2P(O)Ph2}3][CoCl4] in low yield, and this reaction is demonstrated to be prevented under anaerobic conditions representing an unusual example of a reductive dechlorination which only takes place in the presence of oxygen.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2b5a5991361ef6d6f608e1b6c26f1e70 https://doi.org/10.1016/j.jorganchem.2006.05.053 Zobrazit plný text záznamu Full Text from ScienceDirect