Reaction of TiCl4 with solid cyclopentadienylsodium

Autor:	L. I. Red'kina, G. S. Shvindlerman, T. G. Golenko
Rok vydání:	1966
Předmět:	Inert Solvent Cyclopentadienyl complex Chemistry Molecule chemistry.chemical_element General Chemistry Photochemistry Titanium
Zdroj:	Bulletin of the Academy of Sciences, USSR Division of Chemical Science. 15:136-138
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00845856
Popis:	1. A method was proposed for producing (C5H5)2TiCl2 from TiCl4 and solid C5H5Na, suspended in an inert solvent, and conditions were found under which this reaction can be directed toward the formation of C5H5TiCl3. 2. The reaction of TiCl4 with solid C5H5Na, in contrast to the reaction with C5H5Na in solution, proceeds under conditions promoting intermediate formation of cyclopentadienyl compounds of titanium, containing more than two cyclopentadienyl groups in the molecule.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2b53c96c710b598abf9ffe55804fd179 https://doi.org/10.1007/bf00845856 Zobrazit plný text záznamu Full text from SpringerLink