Correlation between XANES of the transition metals in ZnS and ZnSe and their limit of solubility

Autor:	K. Ławniczak-Jabłońska, A. Fontaine, Stefania Pizzini, Agnès Traverse, Z. Gołacki, R.J. Iwanowski
Rok vydání:	1995
Předmět:	Materials science Solid solubility Transition metal Impurity Semiconductor materials Analytical chemistry Limit (mathematics) Electrical and Electronic Engineering Solubility Condensed Matter Physics XANES Electronic Optical and Magnetic Materials Ion
Zdroj:	Physica B: Condensed Matter. :497-499
ISSN:	0921-4526
DOI:	10.1016/0921-4526(94)00732-b
Popis:	Systematic studies of XANES at the K-edge of cations in ZnS, ZnSe and Zn TMS and ZnTMSe compounds with TM being a transition metal (Mn, Fe, Co, Ni) were performed. The concentrationof TM ranged up to their solubility limit. The shape of the K-edge is mainly determined by the type of anion and does not depend on the TM concentration. Three peak structure is found for the cation K-edge in ZnTMS whereas a two peak structure is observed in ZnTMSe. There is a strong correlation between the limit of solid solubility of each TM and their XANES structure. The intensity distribution of TM K-edge reproduces better the shape of the Zn K-edge when the solubility limit of this TM is larger.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2b4f4ad9b64918c7a54ff4a17cbe7ad7 https://doi.org/10.1016/0921-4526(94)00732-b Zobrazit plný text záznamu Full Text from ScienceDirect