Synthesis of RbxC 60 Film by Electrolysis

Autor:	H. Endo, Hiroshi Yamamoto, Nobunari Yoshiyama
Rok vydání:	1996
Předmět:	Electrolysis Chemistry Stereochemistry General Engineering Analytical chemistry General Physics and Astronomy Crystal structure Electrolyte Toluene Chemical reaction law.invention chemistry.chemical_compound symbols.namesake law symbols Thin film Raman spectroscopy Electrolytic process
Zdroj:	Japanese Journal of Applied Physics. 35:L455
ISSN:	1347-4065 0021-4922
DOI:	10.1143/jjap.35.l455
Popis:	An electrolysis process was used to obtain a Rb1C60 film from an organic electrolyte containing C60 molecules. The solution used was a mixture of 0.3 mM–C60, 0.1 N–RbClO4 and N,N-dimethylformamide (DMF)/toluene (1:1). The particles in the obtained film were spindle-shaped and grew to a size of about 1 µ m, depending on the reaction temperature. The Raman spectra of the obtained films indicated the presence of solid C60 and revealed the characteristics of polymeric Rb1C60, the crystal structure of which was confirmed to be body-centered-orthorhombic by X-ray diffraction analysis.
Databáze:	OpenAIRE
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