Synthesis and Reactivity of New Phosphorus-Nitrogen and Phosphorus-Nitrogen-Boron Condensation Monomers

Autor:	Christopher E. Wood, Robert H. Neilson, G. M. Scheide, Rahim Hani, C. E. Davis, David L. Jinkerson, Purnendu Mukherjee
Rok vydání:	1990
Předmět:	Phosphorus Organic Chemistry Thermal decomposition Leaving group chemistry.chemical_element Biochemistry Inorganic Chemistry chemistry.chemical_compound Monomer chemistry Polymerization Organic chemistry Reactivity (chemistry) Boron Phosphazene
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 51:161-164
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426509008040706
Popis:	The preparative chemistry of P-functional N-sllylphosphoranimines, Me3SiN = P(X)R2, and the nature of the phosphazene products of their thermal decomposition are reported with particular emphasis on the effect that the leaving group (X) has on the polymerization/cyclization process. In a related study of potential precursors to novel B-N-P-N polymers, the preparation of a series of new phosphorus-(III) and -01) derivatives of the 1,3,2-diazaboracyclohexane ring system is described.
Databáze:	OpenAIRE
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