A novel and efficient alkyl radical trap in aqueous medium

Autor:	Eric Peralez, Derek H. R. Barton, Marc Jacob
Rok vydání:	1999
Předmět:	inorganic chemicals chemistry.chemical_classification Radical Organic Chemistry Photochemistry Biochemistry Scavenger (chemistry) Diselenide Reaction rate chemistry.chemical_compound chemistry Drug Discovery Halogen Radical disproportionation Derivative (chemistry) Alkyl
Zdroj:	Tetrahedron Letters. 40:9201-9204
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(99)01973-5
Popis:	A simple water soluble diselenide derivative 1 shows radical scavenger properties towards alkyl and hydroxyl radicals (k3 (0°C)=6.8×108 M−1 s−1) in Fenton-type chemistry. The reaction rate between produceded alkyl radicals 2 and the diselenide overwhelms self-termination and halogen transfer reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2b3a21655867ade42d08f7d840b20b3a https://doi.org/10.1016/s0040-4039(99)01973-5 Zobrazit plný text záznamu Full Text from ScienceDirect