Arrhenius parameters for the reaction of propyl radicals with propane

Autor:	G. N. C. Woodall, Harry E. Gunning, Otto P. Strausz, R. E. Berkley
Rok vydání:	1969
Předmět:	Arrhenius equation Radical Organic Chemistry Photodissociation General Chemistry Photochemistry Hydrogen atom abstraction Catalysis chemistry.chemical_compound symbols.namesake chemistry Propane symbols Recombination
Zdroj:	Canadian Journal of Chemistry. 47:3305-3311
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v69-550
Popis:	The reaction of n-propyl radicals from the photolysis of azo-n-propane with propane has been studied and Arrhenius parameters for hydrogen atom abstraction relative to the recombination of n-propyl radicals determined. From the Arrhenius parameters obtained and the available thermodynamic data, the Arrhenius parameters of the reverse reaction, the hydrogen atom abstraction from propane by iso-propyl radicals, have been calculated.Some complicating factors in the photolysis of azopropane are discussed.
Databáze:	OpenAIRE
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