Approach for Introducing a Single Metal Complex into a Polymer Chain: Metallo-Chain Transfer Agents in CO2 or COS/Epoxide Copolymerization Processes
Autor: | Donald J. Darensbourg, Tucker M. Folsom, Ahmed Z. Rashad, Gulzar A. Bhat |
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Rok vydání: | 2019 |
Předmět: |
chemistry.chemical_classification
Polymers and Plastics Organic Chemistry Epoxide Chain transfer 02 engineering and technology Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Inorganic Chemistry Metal chemistry.chemical_compound chemistry Chain (algebraic topology) visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Copolymer 0210 nano-technology Carbonyl sulfide |
Zdroj: | Macromolecules. 52:5217-5222 |
ISSN: | 1520-5835 0024-9297 |
DOI: | 10.1021/acs.macromol.9b00906 |
Popis: | We have designed and synthesized poly(monothiocarbonate)s containing a single well-defined metal complex in the polymers’ backbone via the immortal copolymerization of carbonyl sulfide and propylen... |
Databáze: | OpenAIRE |
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