Stochastic model of adsorption of particles on macromolecules at an arbitrary filling
| Autor: | Zaven E. Navoyan, E. Sh. Mamasakhlisov, V.B. Arakelyan, A. V. Arakelyan, Vladimir F. Morozov |
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| Rok vydání: | 2008 |
| Předmět: |
Physics
Stochastic modelling General Physics and Astronomy Markov process Thermodynamics Context (language use) Variance (accounting) Condensed Matter::Soft Condensed Matter Condensed Matter::Materials Science symbols.namesake Adsorption symbols Physics::Chemical Physics Equilibrium constant Macromolecule |
| Zdroj: | Journal of Contemporary Physics (Armenian Academy of Sciences). 43:48-52 |
| ISSN: | 1934-9378 1068-3372 |
| DOI: | 10.3103/s106833720801009x |
| Popis: | The theory of adsorption of particles on macromolecules is considered. The theory is based on the notion that the adsorption is a discrete Markovian process. In the context of this theory the average number and the variance of the number of ligands adsorbed on macromolecules are calculated exactly. The results are compared with the frequently used approximation where the number of adsorbed particles is smaller than that in the solution. It is shown that for small values of the equilibrium constant the exact and approximate values coincide practically. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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