Pilot plant synthesis of methacrylate copolymer precursors to nonlinear optical materials
| Autor: | J. Markham, J. C. Alonzo, Howard E. Katz, J. E. Sohn, M. P. Bohrer, David A. Mixon, D. I. Cox |
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| Rok vydání: | 1990 |
| Předmět: |
Materials science
Polymers and Plastics Methacrylate copolymer technology industry and agriculture Nonlinear optics General Chemistry Benzoyl peroxide Methacrylate Surfaces Coatings and Films Nonlinear optical Pilot plant Polymer chemistry Materials Chemistry Side chain medicine Copolymer medicine.drug |
| Zdroj: | Journal of Applied Polymer Science. 40:1711-1715 |
| ISSN: | 1097-4628 0021-8995 |
| DOI: | 10.1002/app.1990.070400925 |
| Popis: | The copolymerization of method methacrylate with methacrylates containing anilino side chains was investigated. Azobis (isobutyronitrile) was a better initiator than benzoyl peroxide. Continuous feed of initiator was advantageous compared to adding the initiator all at once. The reaction was scaled up using a 10-L reactor, ultimately yielding hundreds of grams of the desired copolymers, which are valuable precursors to polymeric dyes used in nonlinear optical studies |
| Databáze: | OpenAIRE |
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