Rheological properties of a network model for macromolecular fluids

Autor: F.Th. De Bats, F.W. Wiegel
Rok vydání: 1969
Předmět:
Zdroj: Physica. 43:33-44
ISSN: 0031-8914
DOI: 10.1016/0031-8914(69)90278-x
Popis: A recently proposed model for macromolecular fluids is analysed by making some simplifying assumptions. The derived linear constitutive equation has the form of a time-convolution integral. For oscillatory rectilinear shear flow the frequency-dependent complex viscosity is derived, and it is shown that the model fluid behaves as a Newtonian fluid at very low frequencies, and as an elastic medium at very high frequencies. For rectilinear stationary shear flow the stress is given as a power series in the shear rate. Weissenberg's hypothesis is found to be invalid for this model fluid.
Databáze: OpenAIRE