ChemInform Abstract: Reactions of Ferrocene and Acetylferrocene with Carbon-Centered Free Radicals

Autor:	Enrico Baciocchi, Barbara Floris, E. Muraglia
Rok vydání:	2010
Předmět:	Substitution reaction Chemistry Radical chemistry.chemical_element General Medicine Medicinal chemistry Homolysis chemistry.chemical_compound Ferrocene Nucleophile Electrophile Organic chemistry Acetylferrocene Carbon
Zdroj:	ChemInform. 24
ISSN:	0931-7597
Popis:	Homolytic substitutions of ferrocene with a variety of carbon-centered radicals have been investigated. Reactions with synthetic utility have only been obtained in the cases of ambiphilic radicals (cyanomethyl and alkoxycarbonylmethyl), whereas nucleophilic radicals (R . and RCO . ) give relatively low yields, and no reaction at all is observed with electrophilic radicals (malonyl, methylmalonyl). The reaction of acetylferrocene with cyanomethyl and ethoxycarbonylmethyl radicals leads to the formation of homo- and heteroannular disubstituted products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2a8d975af6a37c14a1022ef8c5c783ca https://doi.org/10.1002/chin.199333237 Zobrazit plný text záznamu Plný text