Ultrafast x‐ray absorption probing of a chemical reaction

Autor:	Ferenc Raksi, Jean-Claude Kieffer, C. Y. Côté, Zhiming Jiang, Abdelaziz Ikhlef, Kent R. Wilson
Rok vydání:	1996
Předmět:	Absorption spectroscopy Chemistry Photodissociation General Physics and Astronomy Photon energy Molecular physics Chemical reaction Molecular dynamics Chemical bond K-edge Physics::Atomic and Molecular Clusters Molecule Physics::Chemical Physics Physical and Theoretical Chemistry
Zdroj:	The Journal of Chemical Physics. 104:6066-6069
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.471305
Popis:	Ultrafast x‐ray techniques can, in principle, allow us to more directly watch the time evolution of matter, with atomic spatial resolution and with time resolution on the scale of atomic motions such as the making and breaking of chemical bonds, in order to more directly observe the fundamental molecular dynamics underlying the concept of ‘‘mechanism’’ in inorganic, organic, and biochemical reactions. As a step toward this goal, we have observed a chemical reaction process, photoinduced dissociation of gas phase SF6 molecules, detected by ultrafast near‐edge x‐ray absorption spectroscopy with time resolutions of 1.5–3 ps, near the sulfur K edge at a photon energy of 2.48 keV (4.98 A).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2a81d126a21d01f0c465d47aadf7875e https://doi.org/10.1063/1.471305 Zobrazit plný text záznamu