Homoleptic lanthanide(ii)–bis(guanidinate) complexes, [Ln(Giso)2] (Giso = [(ArN)2CN(C6H11)2]−, Ar = C6H3Pri2-2,6): planar 4-coordinate (Ln = Sm or Eu) vs distorted tetrahedral (Ln = Yb) geometries

Autor:	Cameron Jones, Andreas Stasch, Dennis Heitmann, Peter C. Junk, Kai-Alexander Lippert
Rok vydání:	2007
Předmět:	Inorganic Chemistry Metal Lanthanide chemistry.chemical_compound Crystallography Planar chemistry visual_art Inorganic chemistry visual_art.visual_art_medium Tetrahedron Homoleptic
Zdroj:	Dalton Trans.. :187-189
ISSN:	1477-9234 1477-9226
DOI:	10.1039/b614028a
Popis:	The first homoleptic lanthanide(II)-guanidinate complexes have been prepared and shown to have differing coordination geometries (including unprecedented examples of planar 4-coordination) that depend on the size of the lanthanide metal.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2a800ed921dd85d6c32f9dbec6d45e83 https://doi.org/10.1039/b614028a Zobrazit plný text záznamu