Synthesis and Magnetic Characterization of [Fe(.eta.5-C9Me7)2].bul.+[A].bul.- (A = TCNE, TCNQ, DDQ). X-ray Structure of [Fe(.eta.5-C9Me7)2].bul.+[TCNQ].bul

Autor:	D. O'Hare, V. J. Murphy
Rok vydání:	1994
Předmět:	Stereochemistry Crystal structure Tetracyanoethylene Magnetic susceptibility Acceptor Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Sandwich compound X-ray crystallography Physical and Theoretical Chemistry Single crystal Monoclinic crystal system
Zdroj:	Inorganic Chemistry. 33:1833-1841
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00087a018
Popis:	Addition of a solution of bis(η 5 -heptamethylindenyl)iron(II) to solutions containing polycyano acceptor molecules (TCNE (tetracyanoethylene), TCNQ (7,7,8,8-tetracyano-p-quinodimethane), or DDQ (2,3-dichloro-5,6-dicyanobenzoquinone)) results in the formation of 1:1 charge-transfer salts with the general composition [Fe(η-C 9 -Me( 7 ) 2 ] .+ °A] .- °A=TCNE, TCNQ, DDQ]. A single crystal X-ray structure determination has been performed for [Fe(η-C 9 Me 7 ) 2 ][TCNQ]. This compound belongs to the monoclinic centrosymmetric space group P2 1 /n
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2a778636b6d49d1048b3323ac9fcba35 https://doi.org/10.1021/ic00087a018 Zobrazit plný text záznamu