Synthesis and Spectral Properties of Unsymmetrically Substituted Mn(II) and Mn(III) Octaethylporphyrins

Autor:	S. V. Zvezdina, N. V. Chizhova, N. Zh. Mamardashvili
Rok vydání:	2020
Předmět:	medicine.diagnostic_test 010405 organic chemistry Chemistry Spectrophotometry Organic Chemistry Spectral properties medicine 01 natural sciences Chloride 0104 chemical sciences Nuclear chemistry medicine.drug
Zdroj:	Russian Journal of Organic Chemistry. 56:1374-1382
ISSN:	1608-3393 1070-4280
DOI:	10.1134/s1070428020080072
Popis:	5-Mononitro-2,3,7,8,12,13,17,18-octaethylporphyrin, 5,10,15-trinitro-2,3,7,8,12,13,17,18-octaethylporphyrin, and their Cd(II) complexes were synthesized. The coordination reactions of 2,3,7,8,12,13,17,18-octaethylporphyrin and its mono- and trinitro-substituted derivatives and the metal-exchange reactions of the synthesized Cd(II) octaethylporphyrin complexes with Mn(II) chloride in DMF were investigated by spectrophotometry. The corresponding Mn(II) and Mn(III) porphyrins were obtained and identified. The kinetic parameters of the studied reactions were determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2a6f6d225c0f484a26cc196937546e3c https://doi.org/10.1134/s1070428020080072 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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