The (water+acetonitrile) mixture revisited: A new approach for calculating partial molar volumes

Autor:	Jorge Alvarez Juliá, Carmen R. Barrero, María del Carmen Grande, Hugo Bianchi, Carlos M. Marschoff
Rok vydání:	2006
Předmět:	Molar Viscosity chemistry.chemical_compound Range (particle radiation) Molar volume Chemistry Thermodynamics General Materials Science Physical and Theoretical Chemistry Classification of discontinuities Acetonitrile Atomic and Molecular Physics and Optics Thermal expansion
Zdroj:	The Journal of Chemical Thermodynamics. 38:760-768
ISSN:	0021-9614
DOI:	10.1016/j.jct.2005.08.009
Popis:	Density and viscosity of (water + acetonitrile) mixtures were measured over the whole composition range at the temperatures: (298.15, 303.15, 308.15, 313.15, and 318.15) K. A new mathematical approach was developed which allows the calculation of the derivatives of density with respect to composition avoiding the appearance of local discontinuities. Thus, reliable partial molar volumes and thermal expansion coefficients were obtained.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2a55ae6d33cc0f0135cc2286df5de0c2 https://doi.org/10.1016/j.jct.2005.08.009 Zobrazit plný text záznamu Full Text from ScienceDirect