ENHANCEMENT OF T[sub C] AND ORTHORHOMBICITY IN ARGON PREHEATED (Y[sub 1−x]Eu[sub x])(SrBa)Cu[sub 3]O[sub 6+z]

Autor: A. Nafidi, B. Bouallal, A. El Kaaouachi, H. Chaib, M. Bellioua, U. (Balu) Balachandran, Kathleen Amm, David Evans, Eric Gregory, Peter Lee, Mike Osofsky, Sastry Pamidi, Chan Park, Judy Wu, Mike Sumption
Rok vydání: 2008
Předmět:
Zdroj: AIP Conference Proceedings.
ISSN: 0094-243X
DOI: 10.1063/1.2900396
Popis: We report here on the preparation, X‐ray diffraction with Rietveld refinement, AC susceptibility measurements and effect of heat treatments in (Y1−xEux)(SrBa)Cu3O6.94. Each sample was subject to two types of heat treatment: oxygen annealing [O] and argon annealing followed by oxygen annealing [AO]. When x increase from 0 to 1, the orthorhombicity e = (b−a)/(b+a) decreases with Tc[O]. However, Tc[AO] decreases with e until x = 0.2 and after it increases by 7 K to 87 K for x = 1 [A,O]. The crystalline parameter b is constant but a (and c) increase indicating an increase of the number of oxygen atoms by chain (NOC) along a axis leading to a decrease of e (Tc) [O] toward a tetragonal structure. The cationic disorder along c decreased for x⩾0.45. For each x, the [AO] treatment increases e (for 0⩽x⩽1), Tc (for x⩾0.45) and the distance d[Cu(1)‐O1] (decrease Tc) for x 0.45. Remarkable correlations were observed. A combination of several factors such as decrease in d[Cu (1)...
Databáze: OpenAIRE