Addition of nitrile oxides to 2,3-dihydrofurylsilanes. Crystal and molecular structure of tetrahydrofuro-[2,3-d]-isoxazolylsilanes

Autor:	I. Zicmane, V. Dirnens, Edmunds Lukevics, A. Kemme, Juris Popelis, N. Pokrovska
Rok vydání:	1999
Předmět:	Silanes Silicon Nitrile Chemistry Stereochemistry Organic Chemistry chemistry.chemical_element Biochemistry Medicinal chemistry Cycloaddition Inorganic Chemistry Crystal chemistry.chemical_compound Acetonitrile oxide Materials Chemistry Molecule Physical and Theoretical Chemistry Enantiomer
Zdroj:	Journal of Organometallic Chemistry. 586:200-207
ISSN:	0022-328X
DOI:	10.1016/s0022-328x(99)00266-1
Popis:	Silylsubstituted tetrahydrofuro-[2,3- d ]-isoxazoles were prepared by the [2+3] cycloaddition of nitrile oxides to 5-(2,3-dihydrofuryl)silanes. Compounds with two condensed bicycles at the silicon atom: bis[6a-(3-methyl-3a,4,5,6a-tetrahydrofuro-[2,3- d ]-isoxazolyl)]dimethyl and bis[6a-(3-methyl-3a,4,5,6a-tetrahydrofuro-[2,3- d ]-isoxazolyl)]diphenylsilanes were prepared by the addition of acetonitrile oxide to the corresponding bis[5-(2,3-dihydrofuryl)]silanes. X-ray analysis demonstrated that 3-methyl-6a-trimethylsilyl-3a,4,5,6a-tetrahydrofuro-[2,3- d ]-isoxazole exists as RR/SS enantiomers, while bis[6a-(3-methyl-3a,4,5,6a-tetrahydrofuro-[2,3- d ]-isoxazolyl)]diphenylsilane-as SSRR/RRSS enantiomers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2a46e87b5fe6617b833f86725d533b6a https://doi.org/10.1016/s0022-328x(99)00266-1 Zobrazit plný text záznamu Full Text from ScienceDirect