A synthesis of 2-vinylcylobutanones using 1-methoxycyclopropyllithium reagents

Autor:	James R. Matz, Theodore Cohen
Rok vydání:	1981
Předmět:	Allylic rearrangement Chemistry Reagent Acid catalyzed Organic Chemistry Drug Discovery Biochemistry Combinatorial chemistry
Zdroj:	Tetrahedron Letters. 22:2455-2458
ISSN:	0040-4039
Popis:	A facile synthesis of 2-vinylcyclobutanones consists of reductive lithiation of 1-phenylthio-1-methoxycyclopropanes) addition of enals or enones to the resulting α-lithioethers, and acid catalyzed rearrangement of the allylic alcohols thus produced.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2a105648e10982c79746172dca8faea5 https://doi.org/10.1016/s0040-4039(01)92931-4 Zobrazit plný text záznamu