Anthraquinone-Catalyzed Photooxidation of Boronic Acids in a Bio-Based Solvent (2-Me-THF)
| Autor: | Christoforos G. Kokotos, Angelos Balaskas, Stamatis K. Serviou, Petros L. Gkizis, Constantinos T. Constantinou, Ierasia Triandafillidi |
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| Rok vydání: | 2023 |
| Předmět: | |
| Zdroj: | Synlett. |
| ISSN: | 1437-2096 0936-5214 |
| DOI: | 10.1055/a-2071-7077 |
| Popis: | The phenol moiety appears in a wide variety of natural products, exhibiting biological activity, and in numerous active pharmaceutical compounds. Boronic acids are potential precursors of the phenol scaffold, and a plethora of efforts has been focused in developing novel and green protocols, targeting their chemoselective transformation into phenols. Photochemistry is a rapidly expanding research field converting light energy into chemical potential. Photochemical aerobic processes possess additional advantages to photochemistry and may find applications in chemical industries. Herein, a low-catalyst-loading anthraquinone-catalyzed photochemical process is demonstrated, under CFL lamp irradiation, while exploiting 2-Me-THF as the reaction medium for the conversion of boronic acids into phenols. Furthermore, a broad substrate scope was employed. |
| Databáze: | OpenAIRE |
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