Synthesis of a novel rigid tetrathiafulvalene-σ-p-benzoquinone diad (TTF-σ-Q) with inherent structural configuration suitable for intramolecular charge-transfer
| Autor: | Alexander I. Shames, Arkady Ellern, Joel Bernstein, Evgeny Tsiperman, Vladimir Khodorkovsky, Lev Shapiro, Tal Regev, J. Y. Becker |
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| Rok vydání: | 1999 |
| Předmět: |
Bent molecular geometry
Metals and Alloys Diad Charge (physics) General Chemistry Benzoquinone Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Crystallography chemistry.chemical_compound chemistry Computational chemistry Covalent bond Intramolecular force Materials Chemistry Ceramics and Composites Moiety Tetrathiafulvalene |
| Zdroj: | Chemical Communications. :1125-1126 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/a902277e |
| Popis: | The synthesis of a novel D–A diad, involving a TTF moiety covalently linked to p-benzoquinone via a rigid spacer, shows a bent structure in the solid state which provides intrinsic through-space intramolecular charge-transfer interaction. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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