Crystalline hydrogen-bonded adducts of dimethyl sulphoxide and 7-hydroxypolyfluoroquinolones (chromones)

Autor: Z. E. Skryabina, Viktor I. Saloutin, Oleg N. Chupakhin, I. T. Bazyl, Grigory G. Aleksandrov
Rok vydání: 1995
Předmět:
Zdroj: Journal of Fluorine Chemistry. 74:15-19
ISSN: 0022-1139
Popis: A stable crystalline hydrogen-bonded adduct of dimethyl sulphoxide (DMSO) and 7-hydroxy-5,6,8-trifluoro-2-carboxychromone has been prepared by the reaction of 2-carboxy-5,6,7,8-tetrafluorochromone with KOH/glycerol in DMSO. It has been found that pentafluorophenol and also 1-cyclohexyl-7-hydroxy-5,6,8-trifluoro-4(1 H )-4-oxoquinoline-2-carboxylic acid form the corresponding crystalline hydrogen-bonded adducts with DMSO. The structure of the latter has been established from an X-ray crystallographic study.
Databáze: OpenAIRE