Hetero-1,3-dipolar cycloadditions of dithiolane-isocyanate imminium methylides: A novel route to 1,3-oxazolidine- and thiazolidine-2-thiones
Autor: | Robin E. Carr, Richard Foster, Colin W. G. Fishwick |
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Rok vydání: | 1996 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 37:711-714 |
ISSN: | 0040-4039 |
DOI: | 10.1016/0040-4039(95)02249-x |
Popis: | Dithiolane-isocyanate imminium methylides which are a new type of azomethine methylide-derived 1,3-dipole undergo efficient and regioselective cycloaddition to conjugated carbonyls and thiocarbonyls to yield predominantly 1,3-oxazolidine- and thiazolidine-2-thiones formed from the initial cycloadducts via loss of thiirane. |
Databáze: | OpenAIRE |
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