Hetero-1,3-dipolar cycloadditions of dithiolane-isocyanate imminium methylides: A novel route to 1,3-oxazolidine- and thiazolidine-2-thiones

Autor: Robin E. Carr, Richard Foster, Colin W. G. Fishwick
Rok vydání: 1996
Předmět:
Zdroj: Tetrahedron Letters. 37:711-714
ISSN: 0040-4039
DOI: 10.1016/0040-4039(95)02249-x
Popis: Dithiolane-isocyanate imminium methylides which are a new type of azomethine methylide-derived 1,3-dipole undergo efficient and regioselective cycloaddition to conjugated carbonyls and thiocarbonyls to yield predominantly 1,3-oxazolidine- and thiazolidine-2-thiones formed from the initial cycloadducts via loss of thiirane.
Databáze: OpenAIRE