Total Synthesis of (-)-Invictolide
| Autor: | Ahmad Al Khazim Al Ghamdi, Attaluri R. Prasad, N. Mallikarjuna Reddy, Jhillu S. Yadav, K. Anantha Lakshmi |
|---|---|
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Synthesis. 44:2595-2600 |
| ISSN: | 1437-210X 0039-7881 |
| Popis: | A convergent approach to the total synthesis of (–)-invictolide, a component of the queen recognition pheromone of Solenopsis invicta, is described. Key steps involve the desymmetrization of a bicyclic olefin with Brown’s chiral hydroboration, C–C bond formation, 1,3-syn reduction, and oxidative lactonization of a 1,3,5-triol with TEMPO/PhI(OAc)2. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|