Stereoselective cycloadditions of chiral acyl-nitroso compounds; palladium(0) catalyzed allylic displacement with concomitant loss of the chiral auxiliary

Autor:	James P. Muxworthy, Garry Procter, James A. Wilkinson
Rok vydání:	1995
Předmět:	Chiral auxiliary Allylic rearrangement Hydroxamic acid Nitroso Compounds organic chemicals Organic Chemistry chemistry.chemical_element Biochemistry Medicinal chemistry Catalysis chemistry.chemical_compound chemistry Nucleophile Drug Discovery Stereoselectivity Palladium
Zdroj:	Tetrahedron Letters. 36:7541-7544
ISSN:	0040-4039
DOI:	10.1016/0040-4039(95)01527-2
Popis:	The methylated diacetate 4, derived from the readily available hydroxamic acid 1, undergoes Pdo catalyzed nucleophilic allylic displacement under conditions which also result in the removal of the chiral auxiliary and its replacement with an easily removed acetyl group.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::29c078cf4d57124ec6949055f3ba2b35 https://doi.org/10.1016/0040-4039(95)01527-2 Zobrazit plný text záznamu Full Text from ScienceDirect