Nonaqueous Electrolytes for Electrochemical Capacitors: Imidazolium Cations and Inorganic Fluorides with Organic Carbonates
| Autor: | Victor R. Koch, Alan B. McEwen, Stephen F. McDevitt |
|---|---|
| Rok vydání: | 1997 |
| Předmět: |
Electrolytic capacitor
chemistry.chemical_classification Renewable Energy Sustainability and the Environment Chemistry Inorganic chemistry Dielectric Electrolyte Conductivity Condensed Matter Physics Electrochemistry Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Hexafluorophosphate Materials Chemistry Thermal stability Alkyl |
| Zdroj: | Journal of The Electrochemical Society. 144:L84-L86 |
| ISSN: | 1945-7111 0013-4651 |
| Popis: | Electrolytes based on 1-ethyl-3-methylimidazolium cation (EMI{sup +}) and either the hexafluorophosphate (EMIPF{sub 6}) or tetrafluorborate (EMIBF{sub 4}) anion in organic alkyl carbonate solvents have been evaluated for use in electrochemical capacitors. The conductivity, capacitance, limiting oxidation and reduction potentials, and thermal stability were assessed. High conductivity and capacitance values were found regardless of whether cyclic (high viscosity/high dielectric constant) or acyclic (low viscosity/low dielectric constant) alkyl carbonates were used. The best correlation with conductivity for the EMIPF{sub 6} salt was found to be the molecular weight and to a lesser degree the viscosity of the solvent. The high specific capacitance (130 F/g) and excellent stability (>3.5 V, >130 C) make these electrolytes well suited for use in electrochemical double-layer capacitors. |
| Databáze: | OpenAIRE |
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