Unique microporous NbO-type CoII/ZnII MOFs from double helical chains: Sorption and luminescent properties
| Autor: | Wen-Wen Dong, Ya-Pan Wu, Jian Zhang, Zhen Peng, Jun Zhao, Liang Xia, Dongsheng Li |
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| Rok vydání: | 2016 |
| Předmět: |
Chemistry
Ligand Bent molecular geometry Inorganic chemistry Sorption 02 engineering and technology Microporous material 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences Electronic Optical and Magnetic Materials Ion Inorganic Chemistry Crystallography Adsorption Materials Chemistry Ceramics and Composites Physical and Theoretical Chemistry 0210 nano-technology Luminescence Natural bond orbital |
| Zdroj: | Journal of Solid State Chemistry. 238:170-174 |
| ISSN: | 0022-4596 |
| Popis: | Under solvothermal conditions, the reactions of CoII/ZnII ions with bent ligand 3-(pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole (4-Hpzpt) afford two compounds {[M(4-pzpt)2] guest}n (guest=H2O, M=CoII (1), ZnII (2)). Both compounds are the thermally and hydrolytically robust 4-connected 3D NbO framework, which formed by double helical chains to give rise to 1D hollow nanochannel with uncoordinated nitrogens completely exposed on the pore surface. Compound 1 exhibits improved N2, CO2 and H2 uptake capacities, while compound 2 displays the strong luminescent emission with obvious red shift. |
| Databáze: | OpenAIRE |
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