Effects of Compatibilizer and Thermoplastic Starch (TPS) Concentration on Morphological, Rheological, Tensile, Thermal and Moisture Sorption Properties of Plasticized Polylactic Acid/TPS Blends
| Autor: | Seyed Mohammad Ali Razavi, Mohammad Reza Abdollahi Moghaddam, Yousef Jahani |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Environmental Engineering Materials science Thermoplastic Polymers and Plastics Moisture Moisture sorption isotherm Sorption 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Equilibrium moisture content 0104 chemical sciences chemistry.chemical_compound Polylactic acid chemistry Ultimate tensile strength Materials Chemistry Thermal stability Composite material 0210 nano-technology |
| Zdroj: | Journal of Polymers and the Environment. 26:3202-3215 |
| ISSN: | 1572-8919 1566-2543 |
| DOI: | 10.1007/s10924-018-1206-7 |
| Popis: | The blends of polylactic acid plasticized with acetyl tributyl citrate (P-PLA) and thermoplastic wheat starch (TPS) were prepared by a co-rotating twin screw extruder and the effect of maleic anhydride grafted PLA (PLA-g-MA) content as reactive compatibilizer on blends compatibility through morphological, rheological and tensile properties of the blends was investigated. Considerable improvement in properties of P-PLA/TPS (70/30 w/w) blend with incorporating the optimum PLA-g-MA content of 4 phr was achieved as this blend exhibited better morphological and rheological properties with an increase by 158 and 276% in tensile strength and elongation at break, respectively, compared to the uncompatibilized blend. Also the thermal stability and moisture sorption properties of the blends as effected by TPS content were studied. Decreasing in thermal stability and increasing in equilibrium moisture content of the blends were observed with progressively increasing of TPS content. For prediction the moisture sorption behaviour of blends with various TPS contents at different relative humidity, the moisture sorption isotherm data were modeled by GAB (Guggenheim–Anderson–de Boer) model. |
| Databáze: | OpenAIRE |
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