Dielectric parameters of mesoporous sieves filled with NaNO2

Autor: S. V. Baryshnikov, Cheng Tien, N. P. Andriyanova, E. V. Stukova, Dieter Michel, E. V. Charnaya
Rok vydání: 2007
Předmět:
Zdroj: Physics of the Solid State. 49:791-795
ISSN: 1090-6460
1063-7834
DOI: 10.1134/s1063783407040324
Popis: This paper reports on a dielectric study of MCM-41 molecular sieves with cellular channels of different sizes filled with the NaNO2 ferroelectric. The temperature dependences of the permittivity and electrical conductivity of sodium nitrite in cellular channels are calculated from experimental data on the permittivity and electrical conductivity of the composite. The calculations are performed using the relationships obtained for the hexagonal matrix with parallel cylindrical inclusions within pores. The observed increase in the conductivity of sodium nitrite in confined geometry at high temperatures is attributed to partial melting. It is shown that the increase in the permittivity of the composite is caused by Maxwell-Wagner relaxation processes.
Databáze: OpenAIRE