Synthesis of thienylhydrogermanes and their transformations in the presence of di(tert-butyl) peroxide
Autor: | S. Grinberga, Edmunds Lukevics, O. A. Pudova, I. Mazheika |
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Rok vydání: | 1997 |
Předmět: | |
Zdroj: | Chemistry of Heterocyclic Compounds. 33:171-174 |
ISSN: | 1573-8353 0009-3122 |
DOI: | 10.1007/bf02256758 |
Popis: | A method was developed for the synthesis of thienylhydrogermanes RnGeH4−n (where R=2-thienyl, n=1–3), involving the reduction of the corresponding ethoxygermanes by lithium aluminum hydride under the conditions of phase-transfer catalysis. The transformations of thienylhydrogermanes under the influence of di(tert-butyl) peroxide were studied. Features of the mass-spectrometric behavior of thienylethoxygermanes were analyzed. |
Databáze: | OpenAIRE |
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