Synthesis of thienylhydrogermanes and their transformations in the presence of di(tert-butyl) peroxide

Autor: S. Grinberga, Edmunds Lukevics, O. A. Pudova, I. Mazheika
Rok vydání: 1997
Předmět:
Zdroj: Chemistry of Heterocyclic Compounds. 33:171-174
ISSN: 1573-8353
0009-3122
DOI: 10.1007/bf02256758
Popis: A method was developed for the synthesis of thienylhydrogermanes RnGeH4−n (where R=2-thienyl, n=1–3), involving the reduction of the corresponding ethoxygermanes by lithium aluminum hydride under the conditions of phase-transfer catalysis. The transformations of thienylhydrogermanes under the influence of di(tert-butyl) peroxide were studied. Features of the mass-spectrometric behavior of thienylethoxygermanes were analyzed.
Databáze: OpenAIRE