Analysis of the latent structure of luminescence and absorption spectra of thallium complexes

Autor:	B. A. Okhrimenko, M. U. Belyi, V. P. Yashchuk, V. N. Bindyukevich, A. S. Kolesnik
Rok vydání:	2000
Předmět:	Photoluminescence Absorption spectroscopy chemistry Excited state Analytical chemistry Thallium chemistry.chemical_element Photoluminescence excitation Condensed Matter Physics Luminescence Absorption (electromagnetic radiation) Spectroscopy Excitation
Zdroj:	Journal of Applied Spectroscopy. 67:95-100
ISSN:	1573-8647 0021-9037
Popis:	Comprehensive investigations of luminescence, excitation, and absorption spectra as well as of the luminescence kinetics of a frozen LiCl-Tl+ solution are carried out. It is established that the luminescence spectrum consists of four components. One component is caused by luminescence of the matrix and the remainder by luminescence of one luminescence center, namely, by the saturated complex of thallium TlCl2(H2O)Cl4. The absorption spectrum consists of three components. Their parameters have been evaluated. Each component of the luminescence spectrum is excited in several components of the absorption spectrum. It is found that the luminescence spectrum components and their intrinsic absorption bands are located differently on the frequency axis. These data are similar to those obtained for other activated solutions of electrolytes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2987702e456616aeac55acc8f8131691 https://doi.org/10.1007/bf02681427 Zobrazit plný text záznamu Full text from SpringerLink