Benzene sorption by a microporous coordination polymer based on a zinc carboxylate

Autor:	Danil N. Dybtsev, E. A. Ukraintseva, Vladimir P. Fedin, Sergey A. Sapchenko, I. M. Ivanov, Denis G. Samsonenko, A. Yu. Manakov
Rok vydání:	2012
Předmět:	Coordination polymer Materials Science (miscellaneous) Inorganic chemistry Sorption Microporous material DABCO Inclusion compound Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Carboxylate Physical and Theoretical Chemistry Benzene Octane
Zdroj:	Russian Journal of Inorganic Chemistry. 57:717-721
ISSN:	1531-8613 0036-0236
Popis:	Benzene vapor sorption by the organometallic coordination polymer [Zn2(bdc)2(dabco)] (H2bdc = benzene-1,4-dicarboxylic acid, dabco = diazabicyclo[2.2.2]octane) is reported. The [Zn2(bdc)2(dabco)] polymer has a high C6H6 sorption capacity of up to 3.8 mol of benzene per formula unit. The heat of sorption has been determined, and its dependence on the composition of the inclusion compound has been investigated. Included benzene molecules are nonequivalent in terms of the energy of their interaction with the metal-organic framework.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::2986be303559808255c191f3dcf70cc1 https://doi.org/10.1134/s0036023612050233 Zobrazit plný text záznamu Full text from SpringerLink