Epoxidation of Cyclohexene With H2O2 and Acetonitrile Catalyzed by Mg–Al Hydrotalcite and Cobalt Modified Hydrotalcites

Autor:	Rodica Zăvoianu, Emilian Angelescu, Ruxandra Bîrjega, Octavian Dumitru Pavel, Rodica Ionescu
Rok vydání:	2009
Předmět:	Hydrotalcite Inorganic chemistry Cyclohexene Epoxide chemistry.chemical_element General Chemistry Heterogeneous catalysis Catalysis chemistry.chemical_compound chemistry Mixed oxide Acetonitrile Cobalt Nuclear chemistry
Zdroj:	Catalysis Letters. 134:309-317
ISSN:	1572-879X 1011-372X
DOI:	10.1007/s10562-009-0238-y
Popis:	The paper presents a comparison between the results obtained for cyclohexene epoxidation in the presence of base catalysts: Mg0/75Al0.25-hydrotalcite (HT), the corresponding mixed oxide (CHT), the reconstructed hydrotalcite (RHT), a hydrotalcite containing cobalt in the brucite-type layer ((Co-Mg0.75)Al0.25)) and one containing cobalt complex-species supported on HT carrier (Co-complex/HT). The selective conversion of cyclohexene to the corresponding epoxide is closely related to the base strength of the catalysts.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::298346e3e50011f28336f33489da5b98 https://doi.org/10.1007/s10562-009-0238-y Zobrazit plný text záznamu Full text from SpringerLink