Synthesis and Magnetic Properties of Barium-Doped Nanocrystal Lanthanum Orthoferrite

Autor: N. S. Perov, A. T. Nguyen, O. V. Almjasheva, L. V. Druzhinina, I. Ya. Mittova, V. O. Mittova, Yu. A. Alekhina, M. V. Berezhnaya
Rok vydání: 2019
Předmět:
Zdroj: Russian Journal of General Chemistry. 89:480-485
ISSN: 1608-3350
1070-3632
DOI: 10.1134/s1070363219030198
Popis: Barium-doped nanocrystalline lanthanum ferrite was synthesized by the method of co-precipitation and subsequent annealing at 1000°C. The maximum degree of doping of La1−xBaxFeO3−x (x = 0.1) was established before the appearance of other phases. The introduction of Ba2+ cations leads to an increase in the average crystallite size from 25±4 nm for x = 0 to 42±4 nm for x = 0.1. The formation of particles characterized by a complex magnetic structure combining two types of magnetic ordering was found. The synthesized samples of (1−x)LaFeO3: xBa2+ (x = 0, 0.075, 0.1, 0.15, 0.2, 0.25) are magnetically hard materials.
Databáze: OpenAIRE