Synthesis and Magnetic Properties of Barium-Doped Nanocrystal Lanthanum Orthoferrite
Autor: | N. S. Perov, A. T. Nguyen, O. V. Almjasheva, L. V. Druzhinina, I. Ya. Mittova, V. O. Mittova, Yu. A. Alekhina, M. V. Berezhnaya |
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Rok vydání: | 2019 |
Předmět: |
Orthoferrite
Magnetic structure 010405 organic chemistry Annealing (metallurgy) Doping Analytical chemistry chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Nanocrystalline material 0104 chemical sciences chemistry.chemical_compound chemistry Nanocrystal Lanthanum Crystallite |
Zdroj: | Russian Journal of General Chemistry. 89:480-485 |
ISSN: | 1608-3350 1070-3632 |
DOI: | 10.1134/s1070363219030198 |
Popis: | Barium-doped nanocrystalline lanthanum ferrite was synthesized by the method of co-precipitation and subsequent annealing at 1000°C. The maximum degree of doping of La1−xBaxFeO3−x (x = 0.1) was established before the appearance of other phases. The introduction of Ba2+ cations leads to an increase in the average crystallite size from 25±4 nm for x = 0 to 42±4 nm for x = 0.1. The formation of particles characterized by a complex magnetic structure combining two types of magnetic ordering was found. The synthesized samples of (1−x)LaFeO3: xBa2+ (x = 0, 0.075, 0.1, 0.15, 0.2, 0.25) are magnetically hard materials. |
Databáze: | OpenAIRE |
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